Dirac Sea
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The Dirac sea is a theoretical model of the
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often di ...
as an infinite sea of particles with
negative energy Negative energy is a concept used in physics to explain the nature of certain fields, including the gravitational field and various quantum field effects. Gravitational potential energy Gravitational potential energy can be defined as being n ...
. It was first postulated by the
British British may refer to: Peoples, culture, and language * British people, nationals or natives of the United Kingdom, British Overseas Territories, and Crown Dependencies. ** Britishness, the British identity and common culture * British English, ...
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate cau ...
Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
in 1930 to explain the anomalous negative-energy
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
s predicted by the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin- massive particles, called "Dirac par ...
for relativistic
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
s (electrons traveling near the speed of light). The positron, the
antimatter In modern physics, antimatter is defined as matter composed of the antiparticles (or "partners") of the corresponding particles in "ordinary" matter. Antimatter occurs in natural processes like cosmic ray collisions and some types of radioac ...
counterpart of the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
, was originally conceived of as a
hole A hole is an opening in or through a particular medium, usually a solid body. Holes occur through natural and artificial processes, and may be useful for various purposes, or may represent a problem needing to be addressed in many fields of en ...
in the Dirac sea, before its experimental discovery in 1932.This was not the original intent of Dirac though, as the title of his 1930 paper (''A Theory of Electrons and Protons'') indicates. But it soon afterwards became clear that the mass of holes must be that of the electron. In hole theory, the solutions with negative time evolution factors are reinterpreted as representing the positron, discovered by Carl Anderson. The interpretation of this result requires a Dirac sea, showing that the Dirac equation is not merely a combination of
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates: # The laws ...
and
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
, but it also implies that the number of particles cannot be conserved. Dirac sea theory has been displaced by quantum field theory, though they are mathematically compatible.


Origins

Similar ideas on holes in crystals had been developed by Soviet physicist
Yakov Frenkel __NOTOC__ Yakov Il'ich Frenkel (russian: Яков Ильич Френкель; 10 February 1894 – 23 January 1952) was a Soviet physicist renowned for his works in the field of condensed matter physics. He is also known as Jacov Frenkel, frequ ...
in 1926, but there is no indication the concept was discussed with Dirac when the two met in a soviet physics Congress in the summer of 1928. The origins of the Dirac sea lie in the
energy spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
of the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin- massive particles, called "Dirac par ...
, an extension of the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
consistent with
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates: # The laws ...
, an equation that Dirac had formulated in 1928. Although this equation was extremely successful in describing electron dynamics, it possesses a rather peculiar feature: for each
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
possessing a positive energy , there is a corresponding state with energy -. This is not a big difficulty when an isolated electron is considered, because its energy is conserved and negative-energy electrons may be left out. However, difficulties arise when effects of the electromagnetic field are considered, because a positive-energy electron would be able to shed energy by continuously emitting
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s, a process that could continue without limit as the electron descends into ever lower energy states. However, real electrons clearly do not behave in this way. Dirac's solution to this was to rely on the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
. Electrons are fermions, and obey the exclusion principle, which means that no two electrons can share a single energy state within an atom. Dirac hypothesized that what we think of as the "
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often di ...
" is actually the state in which ''all'' the negative- energy states are filled, and none of the positive-energy states. Therefore, if we want to introduce a single electron, we would have to put it in a positive-energy state, as all the negative-energy states are occupied. Furthermore, even if the electron loses energy by emitting photons it would be forbidden from dropping below zero energy. Dirac further pointed out that a situation might exist in which all the negative-energy states are occupied except one. This "hole" in the sea of negative-energy electrons would respond to electric fields as though it were a positively charged particle. Initially, Dirac identified this hole as a proton. However,
Robert Oppenheimer J. Robert Oppenheimer (; April 22, 1904 – February 18, 1967) was an American theoretical physicist. A professor of physics at the University of California, Berkeley, Oppenheimer was the wartime head of the Los Alamos Laboratory and is often ...
pointed out that an electron and its hole would be able to annihilate each other, releasing energy on the order of the electron's rest energy in the form of energetic photons; if holes were protons, stable
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
s would not exist. Hermann Weyl also noted that a hole should act as though it has the same
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different eleme ...
as an electron, whereas the proton is about two thousand times heavier. The issue was finally resolved in 1932, when the positron was discovered by Carl Anderson, with all the physical properties predicted for the Dirac hole.


Inelegance of Dirac sea

Despite its success, the idea of the Dirac sea tends not to strike people as very elegant. The existence of the sea implies an infinite negative electric charge filling all of space. In order to make any sense out of this, one must assume that the "bare vacuum" must have an infinite positive charge density which is exactly cancelled by the Dirac sea. Since the absolute energy density is unobservable—the
cosmological constant In cosmology, the cosmological constant (usually denoted by the Greek capital letter lambda: ), alternatively called Einstein's cosmological constant, is the constant coefficient of a term that Albert Einstein temporarily added to his field eq ...
aside—the infinite energy density of the vacuum does not represent a problem. Only changes in the energy density are observable. Geoffrey Landis (author of " Ripples in the Dirac Sea", a hard science fiction short story) also notes that Pauli exclusion does not definitively mean that a filled Dirac sea cannot accept more electrons, since, as
Hilbert David Hilbert (; ; 23 January 1862 – 14 February 1943) was a German mathematician, one of the most influential mathematicians of the 19th and early 20th centuries. Hilbert discovered and developed a broad range of fundamental ideas in many ...
elucidated, a sea of infinite extent can accept new particles even if it is filled. This happens when we have a
chiral anomaly In theoretical physics, a chiral anomaly is the anomalous nonconservation of a chiral current. In everyday terms, it is equivalent to a sealed box that contained equal numbers of left and right-handed bolts, but when opened was found to have mor ...
and a gauge
instanton An instanton (or pseudoparticle) is a notion appearing in theoretical and mathematical physics. An instanton is a classical solution to equations of motion with a finite, non-zero action, either in quantum mechanics or in quantum field theory. Mo ...
. The development of quantum field theory (QFT) in the 1930s made it possible to reformulate the Dirac equation in a way that treats the positron as a "real" particle rather than the absence of a particle, and makes the vacuum the state in which no particles exist instead of an infinite sea of particles. This picture is much more convincing, especially since it recaptures all the valid predictions of the Dirac sea, such as electron-positron annihilation. On the other hand, the field formulation does not eliminate all the difficulties raised by the Dirac sea; in particular the problem of the vacuum possessing infinite energy.


Mathematical expression

Upon solving the free Dirac equation, i\hbar\frac = (c\hat \boldsymbol \alpha \cdot \hat \boldsymbol p + mc^2\hat \beta)\Psi, one finds \Psi_ = N\left(\beginU\\ \fracU\end\right)\frac, where \varepsilon = \pm E_p, \quad E_p = +c\sqrt, \quad \lambda = \sgn \varepsilon for plane wave solutions with -momentum . This is a direct consequence of the relativistic energy-momentum relation E^2=p^2c^2+m^2c^4 upon which the Dirac equation is built. The quantity is a constant column vector and is a normalization constant. The quantity is called the ''time evolution factor'', and its interpretation in similar roles in, for example, the
plane wave In physics, a plane wave is a special case of wave or field: a physical quantity whose value, at any moment, is constant through any plane that is perpendicular to a fixed direction in space. For any position \vec x in space and any time t, ...
solutions of the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
, is the energy of the wave (particle). This interpretation is not immediately available here since it may acquire negative values. A similar situation prevails for the Klein–Gordon equation. In that case, the ''absolute value'' of can be interpreted as the energy of the wave since in the canonical formalism, waves with negative actually have ''positive'' energy . But this is not the case with the Dirac equation. The energy in the canonical formalism associated with negative is .


Modern interpretation

The Dirac sea interpretation and the modern QFT interpretation are related by what may be thought of as a very simple
Bogoliubov transformation In theoretical physics, the Bogoliubov transformation, also known as the Bogoliubov–Valatin transformation, was independently developed in 1958 by Nikolay Bogolyubov and John George Valatin for finding solutions of BCS theory in a homogeneous s ...
, an identification between the creation and annihilation operators of two different free field theories. In the modern interpretation, the field operator for a Dirac spinor is a sum of creation operators and annihilation operators, in a schematic notation: \psi(x) = \sum a^\dagger(k) e^ + a(k)e^ An operator with negative frequency lowers the energy of any state by an amount proportional to the frequency, while operators with positive frequency raise the energy of any state. In the modern interpretation, the positive frequency operators add a positive energy particle, adding to the energy, while the negative frequency operators annihilate a positive energy particle, and lower the energy. For a
fermionic field In quantum field theory, a fermionic field is a quantum field whose quanta are fermions; that is, they obey Fermi–Dirac statistics. Fermionic fields obey canonical anticommutation relations rather than the canonical commutation relations of bos ...
, the
creation operator Creation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually ...
a^\dagger(k) gives zero when the state with momentum k is already filled, while the annihilation operator a(k) gives zero when the state with momentum ''k'' is empty. But then it is possible to reinterpret the annihilation operator as a ''creation'' operator for a
negative energy Negative energy is a concept used in physics to explain the nature of certain fields, including the gravitational field and various quantum field effects. Gravitational potential energy Gravitational potential energy can be defined as being n ...
particle. It still lowers the energy of the vacuum, but in this point of view it does so by creating a negative energy object. This reinterpretation only affects the philosophy. To reproduce the rules for when annihilation in the vacuum gives zero, the notion of "empty" and "filled" must be reversed for the negative energy states. Instead of being states with no antiparticle, these are states that are already filled with a negative energy particle. The price is that there is a nonuniformity in certain expressions, because replacing annihilation with creation adds a constant to the negative energy particle number. The
number operator In quantum mechanics, for systems where the total number of particles may not be preserved, the number operator is the observable that counts the number of particles. The number operator acts on Fock space. Let :, \Psi\rangle_\nu=, \phi_1,\phi_2 ...
for a Fermi field is: N = a^\dagger a = 1 - a a^\dagger which means that if one replaces N by 1−''N'' for
negative energy Negative energy is a concept used in physics to explain the nature of certain fields, including the gravitational field and various quantum field effects. Gravitational potential energy Gravitational potential energy can be defined as being n ...
states, there is a constant shift in quantities like the energy and the charge density, quantities that count the total number of particles. The infinite constant gives the Dirac sea an infinite energy and charge density. The vacuum charge density should be zero, since the vacuum is
Lorentz invariant In a relativistic theory of physics, a Lorentz scalar is an expression, formed from items of the theory, which evaluates to a scalar, invariant under any Lorentz transformation. A Lorentz scalar may be generated from e.g., the scalar product of v ...
, but this is artificial to arrange in Dirac's picture. The way it is done is by passing to the modern interpretation. Dirac's idea is more directly applicable to
solid state physics Solid-state physics is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the l ...
, where the
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
in a
solid Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount o ...
can be regarded as a "sea" of electrons. Holes in this sea indeed occur, and are extremely important for understanding the effects of
semiconductor A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
s, though they are never referred to as "positrons". Unlike in particle physics, there is an underlying positive charge—the charge of the ionic lattice—that cancels out the electric charge of the sea.


Revival in the theory of causal fermion systems

Dirac's original concept of a sea of particles was revived in the theory of
causal fermion system The theory of causal fermion systems is an approach to describe fundamental physics. It provides a unification of the weak, the strong and the electromagnetic forces with gravity at the level of classical field theory. Moreover, it gives qu ...
s, a recent proposal for a unified physical theory. In this approach, the problems of the infinite
vacuum energy Vacuum energy is an underlying background energy that exists in space throughout the entire Universe. The vacuum energy is a special case of zero-point energy that relates to the quantum vacuum. The effects of vacuum energy can be experimental ...
and infinite charge density of the Dirac sea disappear because these divergences drop out of the physical equations formulated via the
causal action principle The theory of causal fermion systems is an approach to describe fundamental physics. It provides a unification of the weak interaction, weak, the strong interaction, strong and the electromagnetism, electromagnetic forces with gravity at the le ...
. These equations do not require a preexisting space-time, making it possible to realize the concept that space-time and all structures therein arise as a result of the collective interaction of the sea states with each other and with the additional particles and "holes" in the sea.


See also

*
Fermi sea A composite fermion is the topological bound state of an electron and an even number of quantized vortices, sometimes visually pictured as the bound state of an electron and, attached, an even number of magnetic flux quanta. Composite fermions we ...
*
Positronium Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two parti ...
*
Vacuum polarization In quantum field theory, and specifically quantum electrodynamics, vacuum polarization describes a process in which a background electromagnetic field produces virtual electron–positron pairs that change the distribution of charges and curr ...
*
Virtual particle A virtual particle is a theoretical transient particle that exhibits some of the characteristics of an ordinary particle, while having its existence limited by the uncertainty principle. The concept of virtual particles arises in the perturbat ...


Remarks


Notes


References

* * * * * (Chapter 12 is dedicate to hole theory.) *{{Cite book, last=Sattler, first=K. D., title=Handbook of Nanophysics: Principles and Methods, pages=10–4, url=https://books.google.com/books?id=G7mq8NBz_ZsC&q=dirac+sea+number+operator+for+a+fermi+field&pg=SA10-PA4, year=2010, publisher=
CRC Press The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information tec ...
, isbn=978-1-4200-7540-3, access-date=2011-10-24 Quantum field theory Vacuum
Sea The sea, connected as the world ocean or simply the ocean, is the body of salty water that covers approximately 71% of the Earth's surface. The word sea is also used to denote second-order sections of the sea, such as the Mediterranean Sea, ...